N-Coordinated Pd–Rh synergy for highly selective ethylene glycol oxidation and efficient hydrogen evolution
Hai-Yan Guo, Jinwei Kang, Yikui Du, Lu Zhang, Jiu‐Ju Feng, Ai‐Jun Wang
Abstract
The N-coordinated PdRh@Ni(OH) 2 catalyst achieves >97.6% GA selectivity and efficient hydrogen evolution (2.52 kW h m −3 H 2 ) via synergistic Pd–Rh interactions and N-coordination, enabling EG adsorption, * OC–CH 2 OH formation and OH − activation.
Topics & Concepts
Ethylene glycolEthyleneChemistryHydrogenCombinatorial chemistryOrganic chemistryCatalysisCatalytic Processes in Materials ScienceElectrocatalysts for Energy ConversionMesoporous Materials and Catalysis