Incorporation of a Phosphino(pyridine) Subcomponent Enables the Formation of Cages with Homobimetallic and Heterobimetallic Vertices
John P. Carpenter, Tanya K. Ronson, Felix J. Rizzuto, Théophile Héliot, Peter Grice, Jonathan R. Nitschke
Abstract
tetrahedral cages, representing an initial example of self-assembled cages containing well-defined heterobimetallic vertices.
Topics & Concepts
ChemistryBimetallic stripOctahedronCrystallographyPyridineStereochemistryMetalTetrahedronCrystal structureOrganic chemistrySupramolecular Chemistry and ComplexesMetal-Organic Frameworks: Synthesis and ApplicationsMolecular Sensors and Ion Detection