Surface accumulation and acid–base equilibrium of phenol at the liquid–vapor interface
Clemens Richter, Rémi Dupuy, Florian Trinter, Tillmann Buttersack, Louisa Cablitz, Shirin Gholami, Dominik Stemer, Christophe Nicolas, Robert Seidel, Bernd Winter, Hendrik Bluhm
Abstract
for phenol and phenolate deviate from those observed for the pure solutions. We discuss these observations in view of the different surface propensity of phenol and phenolate as well as potential cooperative interactions between them in the near-surface region.
Topics & Concepts
PhenolSurface tensionPulmonary surfactantAqueous solutionChemistryX-ray photoelectron spectroscopyJet (fluid)Base (topology)Surface (topology)Chemical engineeringInorganic chemistryPhysical chemistryOrganic chemistryThermodynamicsPhysicsEngineeringMathematicsMathematical analysisGeometryBiochemistrySpectroscopy and Quantum Chemical StudiesSurfactants and Colloidal SystemsElectrostatics and Colloid Interactions