Slow magnetic relaxation and selective luminescence sensor of Ln-radical chain involving imidazole-substituted nitronyl nitroxide radical
Qing Zhong, Huiyang Dong, Yi Liu, Mei Zhu
Abstract
A family of 1D Ln-radical complexes have been obtained in which functionalized NIT-Ph-3-(1-Im) ligand linked Ln III ions in “head-to-tail” mode. Tb complex reveals slow magnetic relaxation and luminescent probe coexisting in a molecular entity.
Topics & Concepts
ChemistryNitroxide mediated radical polymerizationImidazoleLuminescenceMagnetic relaxationRadical ionRelaxation (psychology)PhotochemistryIonLigand (biochemistry)CrystallographyStereochemistryReceptorRadical polymerizationMagnetic fieldOrganic chemistryOptoelectronicsMagnetizationPolymerQuantum mechanicsSocial psychologyPhysicsCopolymerBiochemistryPsychologyMagnetism in coordination complexesLanthanide and Transition Metal ComplexesElectron Spin Resonance Studies