Accelerating symmetry-breaking charge separation in a perylenediimide trimer through a vibronically coherent dimer intermediate
Chenjian Lin, Taeyeon Kim, Jonathan D. Schultz, Ryan M. Young, Michael R. Wasielewski
Topics & Concepts
TrimerVibronic couplingChemistryChromophoreSymmetry breakingChemical physicsDimerExcited stateMolecular physicsMolecular vibrationPolydiacetylenesExcitonCovalent bondCharge (physics)PhotochemistryAtomic physicsMoleculeCondensed matter physicsMonomerPhysicsQuantum mechanicsPolymerOrganic chemistryPorphyrin and Phthalocyanine ChemistryPhotochemistry and Electron Transfer StudiesLuminescence and Fluorescent Materials