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Synthesis of low‐cost microporous activated carbon adsorbents for CO<sub>2</sub> capture from Palmyra palm fruit shell waste biomass

Shobanaboyina Swapna, Manne Parusha Ramudu, Police Vishnuvardhan Reddy, G. Ravi Kumar, Gaddameedi Hima Bindu, Prathap Challa, D. Mallesh

2024Journal of the Chinese Chemical Society11 citationsDOIOpen Access PDF

Abstract

Abstract Using chemical activation techniques at dissimilar carbonization temperatures, activated carbon adsorbents were produced from Palmyra palm fruit biomass in this work. X‐ray diffraction, Fourier transform infrared spectroscopy, X‐ray photoelectron spectroscopy, laser Raman spectroscopy, scanning electron microscopy, CHNS‐elemental analysis, and N 2 adsorption studies were among the characterization techniques used to assess the characteristics of the carbon adsorbents. The carbon adsorbents from Palmyra palm fruit were used to absorb CO 2 in a temperature range of 25–70°C. The findings of the characterization showed that these carbons have a large surface area and microporosity. The temperature of carbonization and the activating agent had an impact on the surface characteristics. The samples with the highest adsorption capacity, 4.70 mmol/g at 25°C, were the activated carbons made by treating them with KOH and then carbonizing them at 750°C. The physicochemical properties of the adsorbents provided an explanation for their high adsorption capacity. The adsorbents showed simple desorption and maintained constant activity during ten cycles of recycling.

Topics & Concepts

ChemistryActivated carbonMicroporous materialBiomass (ecology)AdsorptionShell (structure)Carbon fibersWaste managementPalmPulp and paper industryChemical engineeringEnvironmental chemistryOrganic chemistryAgronomyComposite numberEngineeringBiologyMaterials sciencePhysicsQuantum mechanicsComposite materialCarbon Dioxide Capture TechnologiesPhase Equilibria and ThermodynamicsChemical Looping and Thermochemical Processes