Synthesis, structural characterization, and theoretical analysis of novel zinc(<scp>ii</scp>) schiff base complexes with halogen and hydrogen bonding interactions
Md. Gishan, Puspendu Middya, Michael G. B. Drew, Antonio Frontera, Shouvik Chattopadhyay
Abstract
] units into a one-dimensional supramolecular polymer. This network has been meticulously examined using QTAIM and NCIplot analyses, allowing for an estimation of the hydrogen bond strengths. The significance of H-bonds and CH⋯π interactions in complex 3 was investigated, as these interactions are crucial for the formation of infinite 1D chains in the solid state.
Topics & Concepts
Schiff baseSupramolecular chemistryZincHalogenHydrogen bondChemistrySolid-stateHalogen bondCrystallographyPolymer chemistryMoleculeCrystal structureOrganic chemistryPhysical chemistryAlkylCrystallography and molecular interactionsMetal complexes synthesis and propertiesCrystal structures of chemical compounds