<i>In situ</i> topotactic formation of an inorganic intergrowth bulk NiS/FeS@MgFe-LDH heterojunction to simulate CODH for the photocatalytic reduction of CO<sub>2</sub>
Yuexian Li, Wenli Su, Xiaoyan Wang, Jun Lu, Wenkai Zhang, Shuo Wei
Abstract
By using of the structural memory effect of LDHs, an inorganic intergrowth bulk heterojunction NiS/FeS@MgFe-LDHs mimic active C-clusters [Ni–4Fe–4S] in Carbon monoxide dehydrogenase, in which unique photogenerated electron transfer channel encouraged carrier separation.
Topics & Concepts
HeterojunctionPhotocatalysisIn situMaterials scienceReduction (mathematics)NanotechnologyChemical engineeringChemistryOptoelectronicsCatalysisEngineeringBiochemistryOrganic chemistryMathematicsGeometryAdvanced Photocatalysis TechniquesLayered Double Hydroxides Synthesis and ApplicationsCO2 Reduction Techniques and Catalysts