Insights into Self-Assembly of Nonplanar Molecules with Aggregation-Induced Emission Characteristics
Jie Li, Jianyu Zhang, Jianxin Wang, Dong Wang, Yun Yan, Jianbin Huang, Ben Zhong Tang
Abstract
Utilizing nonplanar conjugated molecules as building blocks facilitates the development of self-assembly but is fundamentally challenging. To study the self-assembly behavior, we herein demonstrate the self-assembly process of a nonplanar conjugated molecule with aggregation-induced emission (AIE) feature from an isolated molecule to an irregular cluster to a well-defined vesicle driven by amphiphiles. The superhigh aggregation-sensitive emission affords more precise and detailed information about the self-assembly process than traditional dyes. Meanwhile, the arrangements of the AIE-active molecule change from disordered to well-organized forms by reducing the twisted configuration during the transformation process, and the strong hydrophobicity of amphiphiles is crucial for such configuration and morphology transformations. Owing to the thermophilic bacteria-mimetic membranes, the obtained vesicles exhibit a property of superhigh thermal stability. They also display promising light-harvesting applications. This work not only deciphers the self-assembly of AIE molecules but also provides a strategy for nonplanar molecules to build well-organized self-assemblies.