Guanidinylated SBA-15/Fe3O4 mesoporous nanocomposite as an efficient catalyst for the synthesis of pyranopyrazole derivatives
Fereshte Hassanzadeh‐Afruzi, Somayeh Asgharnasl, Sara Mehraeen, Zeinab Amiri-Khamakani, Ali Maleki
Abstract
Abstract In this study, a novel mesoporous nanocomposite was fabricated in several steps. In this regard, SBA-15 was prepared by the hydrothermal method, next it was magnetized by in-situ preparation of Fe 3 O 4 MNPs. After that, the as-prepared SBA-15/Fe 3 O 4 functionalized with 3-minopropyltriethoxysilane (APTES) via post-synthesis approach. Then, the guanidinylated SBA-15/Fe 3 O 4 was obtained by nucleophilic addition of APTES@SBA-15/Fe 3 O 4 to cyanimide. The prepared nanocomposite exhibited excellent catalytic activity in the synthesis of dihydropyrano[2,3-c]pyrazole derivatives which can be related to its physicochemical features such as strong basic sites (presented in guanidine group), Lewis acid site (presented in Fe 3 O 4 ), high porous structure, and high surface area. The characterization of the prepared mesoporous nanocomposite was well accomplished by different techniques such as FT-IR, EDX, FESEM, TEM, VSM, TGA, XRD and BET. Furthermore, the magnetic catalyst was reused at least six consequent runs without considerable reduction in its catalytic activity.