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An Optimized Microscale Thermophoresis Method for High-Throughput Screening of DNA Methyltransferase 2 Ligands

Robert A. Zimmermann, Marvin Schwickert, J. Laurenz Meidner, Zarina Nidoieva, Mark Helm, Tanja Schirmeister

2022ACS Pharmacology & Translational Science24 citationsDOIOpen Access PDF

Abstract

-adenosylhomocysteine derivative, 5-FAM-triazolyl-adenosyl-Dab, developed for a fluorescence polarization assay to investigate the histone methyltransferase mixed-lineage leukemia 1, we herein describe the applicability of this compound as a fluorescent tracer for the investigation of DNA-methyltransferase 2 (DNMT2), a human RNA methyltransferase. Based on these findings, we established a microscale thermophoresis (MST) assay for DNMT2. This displacement assay can circumvent various problems inherent to this method. Furthermore, we optimized a screening method via MST which even indicates if the detected binding is competitive and gives the opportunity to estimate the potency of a ligand, both of which are not possible with a direct binding assay.

Topics & Concepts

Microscale thermophoresisMethyltransferaseChemistryDNA methyltransferaseDNAFluorescenceMicroscale chemistryBiochemistryMethylationQuantum mechanicsMathematicsMathematics educationPhysicsNanopore and Nanochannel Transport StudiesHybrid Renewable Energy SystemsDNA and Nucleic Acid Chemistry
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