Liquid metal synthesis solvents for metallic crystals
Shuhada A. Idrus‐Saidi, Jianbo Tang, Stephanie Lambie, Jialuo Han, Mohannad Mayyas, Mohammad B. Ghasemian, Francois‐Marie Allioux, Shengxiang Cai, Pramod Koshy, Peyman Mostaghimi, Krista G. Steenbergen, Amanda S. Barnard, Torben Daeneke, Nicola Gaston, Kourosh Kalantar‐Zadeh
Abstract
In nature, snowflake ice crystals arrange themselves into diverse symmetrical six-sided structures. We show an analogy of this when zinc (Zn) dissolves and crystallizes in liquid gallium (Ga). The low-melting-temperature Ga is used as a "metallic solvent" to synthesize a range of flake-like Zn crystals. We extract these metallic crystals from the liquid metal solvent by reducing its surface tension using a combination of electrocapillary modulation and vacuum filtration. The liquid metal-grown crystals feature high morphological diversity and persistent symmetry. The concept is expanded to other single and binary metal solutes and Ga-based solvents, with the growth mechanisms elucidated through ab initio simulation of interfacial stability. This strategy offers general routes for creating highly crystalline, shape-controlled metallic or multimetallic fine structures from liquid metal solvents.