Metathesis reactions of Re( <scp>v</scp> ) carbyne complexes with functionalized terminal alkynes
B. Kevin Park, Wei Bai, Lam Cheung Kong, Herman H. Y. Sung, Ian D. Williams, Guochen Jia
Abstract
d 2 Re( v ) carbyne complexes Re(CR)Cl 2 (PMePh 2 ) 3 , can undergo stoichiometric metathesis with a range of terminal aryl and aliphatic alkynes (HCCR′), yielding substituted carbyne complexes Re(CR′)Cl 2 (PMePh 2 ) 3 and HCCR.
Topics & Concepts
CarbyneTerminal (telecommunication)MetathesisChemistrySalt metathesis reactionStereochemistryCatalysisOrganic chemistryCarbenePolymerPolymerizationComputer scienceTelecommunicationsSynthetic Organic Chemistry MethodsOrganometallic Complex Synthesis and CatalysisCatalytic Alkyne Reactions