Cellulose-Based Irreversible Hydrogels Used for CO<sub>2</sub> Sequestration
Dianguo Wu, Yan Zhang, Junjie Huang, Xuezhi Zhao, Baoliang Peng, Weidong Liu, Yujun Feng
Abstract
CO 2 -switchable hydrogels have been well documented during the past decade; however, the reversible response makes them unable to sequestrate CO 2 owing to the gas release and viscosity reduction under high temperatures, weakening their capacity to absorb CO 2 . To address this issue, a series of copolymers based on grafting poly(dimethylaminopropyl methacrylamide) onto the backbone of sodium carboxymethyl cellulose (NaCMC) were prepared, characterized, and examined rheologically. In the semidilute entangled regime, the copolymer aqueous solutions can be gelled in the presence of CO 2, but they cannot revert to the solution phase after bubbling N 2 at 60 °C. With such irreversibility, 1 wt % aqueous solution of the copolymer with 24.88 mol % DMAPMAm can absorb CO 2 up to 12.1 mg·g –1, whereas only 18.2% of the absorbed CO 2 is released after heating at 60 °C. This work paves a new way to develop irreversible hydrogels for CO 2 sequestration.