Interface Engineering of Silicon/Carbon Thin-Film Anodes for High-Rate Lithium-Ion Batteries
Ling Tong, Pan Wang, Wenzhong Fang, Xiaojiao Guo, Wenzhong Bao, Yu Yang, Shi‐Li Shen, Feng Qiu
Abstract
Silicon is one of the most promising alternative active materials for next-generation lithium-ion battery (LIB) applications due to its advantage of high specific capacity. However, the enormous volume variations during lithiation/delithiation still remain to be an obstacle to commercialization. In this work, binder-free pure silicon and silicon/carbon (Si/C) multilayer thin-film electrodes, prepared by scalable one-step magnetron sputtering, are systematically investigated by an interlayer strategy. Herein, we present a rationally structural modification by an amorphous carbon film to enhance the electrical conductivity, mechanical integrity, and electrochemical performance of Si film-based LIBs. Therefore, to maintain the consistency of the direct-contact layer with the electrolyte and current collection, symmetrical Si/C/Si and Si/C/Si/C/Si/C/Si electrodes are deliberately designed to study the influence of embedded carbon. An anode with a carbon content of 10.38 wt % yields an initial discharge specific capacity of 1888.74 mAh g–1 and a capacity retention of 96.82% (1243.56 mAh g–1) after 150 cycles at a high current density of 4000 mA g–1. It also shows that the best rate capability remains 96.0% of the initial capacity in the 70th cycle. At last, three mechanisms are proposed for an in-depth understanding of the interface effect. This work offers a new perspective scheme toward Si/C-based LIBs with a capability of high rate and high energy density.