Indirect Access to Carbene Adducts of Bismuth- and Antimony-Substituted Phosphaketene and Their Unusual Thermal Transformation to Dipnictines and [(NHC)<sub>2</sub>OCP][OCP]
Jacob E. Walley, Levi S. Warring, Erik Kertész, Guocang Wang, Diane A. Dickie, Zoltán Benkő, Robert J. Gilliard
Abstract
and the mechanism of formation were investigated using density functional theory (DFT).
Topics & Concepts
ChemistryCarbeneAdductAntimonyPnictogenReactivity (psychology)BismuthLigand (biochemistry)Oxidation stateMedicinal chemistryCrystallographyInorganic chemistryStereochemistryMetalOrganic chemistryCatalysisAlternative medicinePathologyBiochemistryQuantum mechanicsMedicinePhysicsReceptorSuperconductivitySynthesis and characterization of novel inorganic/organometallic compoundsN-Heterocyclic Carbenes in Organic and Inorganic ChemistryOrganometallic Complex Synthesis and Catalysis