Triggering n→π∗ electronic transitions by thiazole modified graphitic carbon nitride for enhanced photocatalytic hydrogen peroxide production and Rhodamine B degradation
Huagen Liang, Qingyuan Xu, Ruolin Cheng, Shengyu Jing, Chen Fu, Panagiotis Tsiakaras
Abstract
Graphitic carbon nitride (g-C 3 N 4 , GCN) catalyst is widely used in photocatalytic oxygen reduction for hydrogen peroxide (H 2 O 2 ) production and photocatalytic degradation of pollutants. However, its photocatalytic activity is restricted by its narrow light response range and low efficiency of photogenerated charge disjunction and transfer. In this work, thiazole modified g-C 3 N 4 is prepared by Schiff-base condensation reaction of benzothiazole-2-carboxaldehyde (2-BTCA) and CN. It was found that grafting thiazole structures onto the conjugated polymer effectively alter the original symmetrical structure of carbon nitride, thereby triggering n→π* electronic transitions, intensifying light absorption capability, and increasing the charge carrier migration rate. Benefiting from these advantages, the H 2 O 2 yield catalyzed by thiazole modified g-C 3 N 4 (SCN-5) reaches up to 513.2 μmol L -1 within 90 min, which is about 2.2 times that of pure g-C 3 N 4 . Because of this, thiazole ring modified g-C 3 N 4 can be efficiently degrade dye pollutants, for instance remove within 60 minutes up to 96.0% of Rhodamine B (RhB), which is remarkably greater than that obtained with pure g-C 3 N 4 (66.2%). Both density functional theory (DFT) calculations and experimental results demonstrate that the introduction of thiazole rings improves adsorption capacity for O 2 and RhB molecules. This facilitates the production of •O 2 - and enhances the activation and degradation of RhB molecules, thereby boosting photocatalytic performance. This research provides an effective new strategy for improving oxygen activation and offers a straightforward method for practical application of bifunctional photocatalysts.