Photoredox-catalyzed intermolecular azidosulfonylation of alkenes with DABCO·(SO<sub>2</sub>)<sub>2</sub>, trimethylsilyl azide and thianthrenium salts
Huiling Ma, Yanzhi Li, Peiqi Wang, Jiamin Ye, Jun Zhang, Gang Liu, Jie Wu
Abstract
Synthesis of β-azido alkylsulfones through a photoredox-catalyzed azido sulfonylation of alkenes with DABCO·(SO 2 ) 2 , trimethylsilyl azide and alkyl thianthrenium salts is developed.
Topics & Concepts
DABCOChemistryAzideTrimethylsilyl azideAlkylIntermolecular forceCatalysisTrimethylsilylOrganic chemistryMedicinal chemistryPhotochemistryMoleculeSulfur-Based Synthesis TechniquesCyberloafing and Workplace BehaviorChemical Synthesis and Reactions