Synthesis and Frictional Characteristics of Bio-Based Lubricants Obtained from Fatty Acids of Castor Oil
Paulo Roberto Campos Flexa Ribeiro Filho, Matheus Rocha do Nascimento, Silvia Shelly Otaviano da Silva, F. Murilo T. Luna, Enrique Rodrı́guez-Castellón, Célio L. Cavalcante
Abstract
The depletion of oil reserves and concerns about the environmental impact of the use and incorrect disposal of mineral lubricants have been promoting the development of bio-based lubricants. In this study, biolubricants obtained from fatty acids of castor oil were synthesized by esterification (>wt.%93), epoxidation (>wt.%92), and oxirane ring opening reactions using water (>wt.%92) or 2-ethylhexanol (>wt.%94) as nucleophilic agents. The frictional characteristics of the synthesized samples were obtained through tribological tests performed in a four-ball tester and compared with a commercial mineral oil. The sample obtained through oxirane ring opening with water showed the best frictional performance (FC = 0.0699 ± 0.0007) among the prepared samples, with equivalent wear rate (WSD = 281.2 ± 5.54 μm) and ca. 20% lower friction coefficient when compared to the commercial mineral oil, indicating its great potential for replacing mineral fossil oils.