Dual hydrogen-bond donor group-containing Zn-MOF for the highly effective coupling of CO<sub>2</sub>and epoxides under mild and solvent-free conditions
Ziyu Gao, Xiao Zhang, Ping Xu, Jianmin Sun
Abstract
A novel 3D Zn<sub>3</sub>(L)<sub>3</sub>(H<sub>2</sub>L) MOF with dual hydrogen-bond donor (HBD) groups exhibited an efficient catalytic performance for the CO<sub>2</sub>cycloaddition with epoxides under 80 °C, 1.0 MPa and solvent-free conditions.
Topics & Concepts
CycloadditionCatalysisHydrogen bondChemistrySolventGroup (periodic table)HydrogenPolymer chemistryOrganic chemistryMoleculeCarbon dioxide utilization in catalysisMetal-Organic Frameworks: Synthesis and ApplicationsChemical Synthesis and Reactions