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Mechanism of Two Typical Binders BR and F<sub>2604</sub> on Thermal Decomposition of HMX

Wanxiao Guo, Yaning Li, Wei Xiao, Jian Li, Zhiwei Han, Boliang Wang

2021ACS Omega15 citationsDOIOpen Access PDF

Abstract

can induce premature decomposition of HMX and increase the activation energy of HMX. Especially in the case of HMX/BR particles, the decomposition temperature is the lowest, but the activation energy is the highest. Based on the results of DSC-TG-FTIR-MS, it is found that the rapid mechanism of binder and active intermediate products inhibits the reaction of relatively inert intermediate products and prolongs the continuous generation time of gas products in the composite particles, which delays the decomposition of HMX to a certain extent. This study is helpful for us to better understand the thermal decomposition behavior of HMX composite particles and provides reference for the application of high-energy composites.

Topics & Concepts

Thermal decompositionDecompositionActivation energyInertFourier transform infrared spectroscopyComposite numberMaterials scienceChemical engineeringEnergetic materialInert gasReaction mechanismMechanism (biology)ChemistryPhysical chemistryComposite materialOrganic chemistryCatalysisPhysicsExplosive materialEngineeringQuantum mechanicsEnergetic Materials and CombustionThermal and Kinetic AnalysisFlame retardant materials and properties
Mechanism of Two Typical Binders BR and F<sub>2604</sub> on Thermal Decomposition of HMX | Litcius