Charge-assisted hydrogen bond and nitrile⋯nitrile interaction directed supramolecular associations in Cu(<scp>ii</scp>) and Mn(<scp>ii</scp>) coordination complexes: anticancer, hematotoxicity and theoretical studies
Pranay Sharma, Anshuman Gogoi, Akalesh K. Verma, Antonio Frontera, Manjit K. Bhattacharyya
Abstract
Charge-assisted H-bonds and nitrile⋯nitrile interactions directed assemblies in Cu(<sc>ii</sc>) and Mn(<sc>ii</sc>) complexes have been analyzed by MEP surface and NCI plot index. Anticancer activities and hematotoxictiy have been investigated.
Topics & Concepts
ChemistryNitrileHydrogen bondSupramolecular chemistryStereochemistryCrystallographyMedicinal chemistryMoleculeOrganic chemistryCrystal structureMetal complexes synthesis and propertiesMetal-Organic Frameworks: Synthesis and ApplicationsCrystallography and molecular interactions