Photophysical Integrity of the Iron(III) Scorpionate Framework in Iron(III)–NHC Complexes with Long-Lived <sup>2</sup>LMCT Excited States
Om Prakash, Linnea Lindh, Nidhi Kaul, Nils W. Rosemann, Iria Bolaño Losada, Catherine Johnson, Pavel Chábera, Aleksandra Ilic, Jesper Schwarz, Arvind Kumar Gupta, Jens Uhlig, Tore Ericsson, Lennart Häggström, Ping Huang, Jesper Bendix, Daniel Strand, Arkady Yartsev, Reiner Lomoth, Petter Persson, Kenneth Wärnmark
Abstract
(2.0 ns and 2.1%). The integrity of the favorable excited state characteristics upon substitution of the ligand framework demonstrates the robustness of the scorpionate motif that tolerates modifications in the 4-phenyl position for applications such as the attachment in molecular or hybrid assemblies.
Topics & Concepts
ChemistryExcited statePhotochemistryAtomic physicsPhysicsCO2 Reduction Techniques and CatalystsRadical Photochemical ReactionsAdvanced Photocatalysis Techniques