A dual responsive photonic liquid for independent modulation of color brightness and hue
Yun Liu, Qingsong Fan, Guanghao Zhu, Gongpu Shi, Huiru Ma, Wei Li, Tianlong Wu, Jitao Chen, Yadong Yin, Jianguo Guan
Abstract
@polyvinylpyrrolidone (PVP)@poly(N-isopropyl acrylamide) (PNIPAM) flexible photonic nanochains. The underlying modulation mechanism of color brightness was experimentally and numerically deciphered by analyzing the morphological responses to stimuli. When an increasing magnetic field was applied, the random worm-like flexible photonic nanochains gradually orientated along the field direction, due to the dominant magnetic dipole interaction over the thermal motion, lengthening the orientation segment length up to the whole of the nanochains. Consequently, the suspension displays increased color brightness (characterized by diffraction intensity). Meanwhile, the color hue (characterized by diffraction frequency) could be controlled by temperature, due to the volume changes of the interparticle PNIPAM. The achieved diverse color modulation advances the next-generation responsive chromic materials and enriches the basic understanding of the color tuning mechanisms. With versatile and facile color tunability and shape patterning, the developed responsive chromic liquid promises to have attractive potential in full-color displays and in adaptive camouflages.