Syntheses of new chiral chimeric photo-organocatalysts
Jiyaun Lyu, Matteo Leone, Aurélie Claraz, Clémence Allain, Luc Neuville, Géraldine Masson
Abstract
A new family of chiral chimeric photo-organocatalysts derived from phosphoric acid were synthesized and their spectroscopic and electrochemical properties were investigated. Then, the ability of these photo-activable molecules to catalyse an asymmetric tandem electrophilic β-amination of enecarbamates was evaluated.
Topics & Concepts
AminationElectrophilic aminationPhosphoric acidChemistryTandemCombinatorial chemistryElectrophileElectrochemistryOrganocatalysisMoleculeOrganic chemistryEnantioselective synthesisCatalysisMaterials sciencePhysical chemistryComposite materialElectrodeRadical Photochemical ReactionsOxidative Organic Chemistry ReactionsFluorine in Organic Chemistry