A rigid-flexible double-layer steric strategy for ethylene (co)oligomerization with pyridine-imine Ni(<scp>ii</scp>) and Pd(<scp>ii</scp>) complexes
Zhengpeng Yan, Huiqin Bi, Beihang Ding, Hui Wang, Guoyong Xu, Shengyu Dai
Abstract
A rigid-flexible double-layer steric strategy enhances the molecular weight of the resulting ethylene oligomers and promotes the co-oligomerization of ethylene and methyl acrylate.
Topics & Concepts
ChemistrySteric effectsEthyleneImineAcrylateMethyl acrylatePyridineLayer (electronics)Polymer chemistryStereochemistryMedicinal chemistryOrganic chemistryCatalysisPolymerCopolymerOrganometallic Complex Synthesis and CatalysisSynthetic Organic Chemistry MethodsAsymmetric Hydrogenation and Catalysis