Heterogeneous Ru/TiO<sub>2</sub> for hydroaminomethylation of olefins: multicomponent synthesis of amines
Jinghua An, Zhuyan Gao, Yehong Wang, Zhixin Zhang, Jian Zhang, Lu Li, Bo Tang, Feng Wang
Abstract
Heterogeneous Ru/TiO<sub>2</sub>-catalyzed HAM reaction of olefins is developed. Various amines can be obtained from olefins. The lower electron density of the Ru<sup>δ+</sup> and the higher amount of acid sites of Ru/TiO<sub>2</sub>, lead to the high HAM reaction activity.
Topics & Concepts
ChemistryCatalysisHeterogeneous catalysisRutheniumOrganic chemistryAsymmetric Hydrogenation and CatalysisCarbon dioxide utilization in catalysisNanomaterials for catalytic reactions