Cobalt-catalyzed radical-mediated carbon–carbon scission <i>via</i> a radical-type migratory insertion
Jian‐Biao Liu, Xiaojun Liu, João C. A. Oliveira, Dezhan Chen, Lutz Ackermann
Abstract
the proton-coupled electron transfer (PCET) mechanism rather than the originally proposed concerted metalation-deprotonation (CMD) pathway. The ring opening strategy may stimulate further development and discovery of novel radical transformations.
Topics & Concepts
CobaltCatalysisChemistryBond cleavageCarbon fibersPhotochemistryMigratory insertionOrganic chemistryMaterials scienceComposite materialComposite numberCatalytic C–H Functionalization MethodsCyclopropane Reaction MechanismsCatalytic Cross-Coupling Reactions