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Unexpected chirality transition and inversion mediated by dissolution–aggregation and the odd–even effect

Yafei Ma, Xiaoxiao Cheng, Haotian Ma, Zixiang He, Zhengbiao Zhang, Wei Zhang

2022Chemical Science39 citationsDOIOpen Access PDF

Abstract

Unexpected chirality transition and inversion at molecular, macromolecular and supramolecular levels were realized by dissolution–aggregation and the odd–even effect, which is helpful for the design of advanced chirality-controllable materials.

Topics & Concepts

Supramolecular chiralityStereocenterSupramolecular chemistryChirality (physics)AzobenzeneMacromoleculeChemical physicsPolymerInversion (geology)ChemistryMaterials scienceCrystallographyEnantioselective synthesisOrganic chemistryPhysicsCrystal structureBiochemistryChiral symmetry breakingQuarkBiologyStructural basinQuantum mechanicsCatalysisPaleontologyNambu–Jona-Lasinio modelSynthesis and Properties of Aromatic CompoundsSupramolecular Self-Assembly in MaterialsPhotochromic and Fluorescence Chemistry
Unexpected chirality transition and inversion mediated by dissolution–aggregation and the odd–even effect | Litcius