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Water‐Soluble Non‐Classical Benzene Mimetics

Vadym V. Levterov, Yaroslav Panasyuk, Valentyna O. Pivnytska, Pavel K. Mykhailiuk

2020Angewandte Chemie31 citationsDOI

Abstract

Abstract A new generation of saturated benzene mimetics, 2‐oxabicyclo[2.1.1]hexanes, was developed. These compounds were designed as analogues of bicyclo[1.1.1]pentane with an improved water solubility. Crystallographic analysis of 2‐oxabicyclo[2.1.1]hexanes revealed that they occupy a novel chemical space, but, at the same time, resemble the motif of meta ‐disubstituted benzenes.

Topics & Concepts

BenzeneSolubilityPentaneChemistryWater solubleBicyclic moleculeStereochemistryOrganic chemistryMedicinal chemistrySynthesis and Properties of Aromatic CompoundsPorphyrin and Phthalocyanine ChemistrySynthetic Organic Chemistry Methods
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