Catalytic hydrogenation enabled by ligand-based storage of hydrogen
Andrew J. McNeece, Kate A. Jesse, Alexander S. Filatov, Joseph E. Schneider, John S. Anderson
Abstract
Using inspiration from biological cofactors, the reversible storage of hydrogen on a supporting dihydrazonopyrrole ligand enables catalytic hydrogenation reactivity with nickel.
Topics & Concepts
CatalysisLigand (biochemistry)ChemistryCoordination sphereCombinatorial chemistryElectron transferRedoxHydrogen storageMetalHydrogen atomHydrogenPhotochemistryOrganic chemistryReceptorAlkylBiochemistryMetalloenzymes and iron-sulfur proteinsCO2 Reduction Techniques and CatalystsAsymmetric Hydrogenation and Catalysis