Low-Resistive Source/Drain Formation Using Nitrogen Plasma Treatment in Self-Aligned In-Ga-Zn-Sn-O Thin-Film Transistors
Hiroshi Tsuji, Tatsuya Takei, Mototaka Ochi, Masashi Miyakawa, Kohei Nishiyama, Yoshiki Nakajima, Mitsuru Nakata
Abstract
In this work, we demonstrate the effectiveness of nitrogen plasma treatment on the formation of low-resistive source/drain (S/D) in self-aligned (SA) oxide thin-film transistors (TFTs) using a high-mobility oxide semiconductor (OS), In-Ga-Zn-Sn-O (IGZTO). The nitrogen plasma treatment was more effective at reducing the sheet resistance ( <inline-formula xmlns:mml="http://www.w3.org/1998/Math/MathML" xmlns:xlink="http://www.w3.org/1999/xlink"> <tex-math notation="LaTeX">${R} _{\mathrm{ sheet}}$ </tex-math></inline-formula> ) of IGZTO films than the commonly used argon plasma treatment. Furthermore, <inline-formula xmlns:mml="http://www.w3.org/1998/Math/MathML" xmlns:xlink="http://www.w3.org/1999/xlink"> <tex-math notation="LaTeX">${R} _{\mathrm{ sheet}}$ </tex-math></inline-formula> for nitrogen-plasma-treated IGZTO films remained low, even when the RF power and radiation time during the plasma treatment were increased when the minimum <inline-formula xmlns:mml="http://www.w3.org/1998/Math/MathML" xmlns:xlink="http://www.w3.org/1999/xlink"> <tex-math notation="LaTeX">${R} _{\mathrm{ sheet}}$ </tex-math></inline-formula> was achieved. The same trends were also observed in OS films with different compositions, such as In-Ga-Zn-O and In-Sn-Zn-O. These results indicate that nitrogen plasma treatment is effective for achieving a reduction of <inline-formula xmlns:mml="http://www.w3.org/1998/Math/MathML" xmlns:xlink="http://www.w3.org/1999/xlink"> <tex-math notation="LaTeX">${R} _{\mathrm{ sheet}}$ </tex-math></inline-formula> for various OS films with a wide process window regarding plasma processing parameters. The advantages could be attributed to the smaller sputtering effect on the OS films due to the lower mass of nitrogen ions than argon ions, which was verified by X-ray reflectivity and X-ray photoelectron spectroscopy analyses. For further validation, SA IGZTO TFTs with a channel length ( <inline-formula xmlns:mml="http://www.w3.org/1998/Math/MathML" xmlns:xlink="http://www.w3.org/1999/xlink"> <tex-math notation="LaTeX">${L}$ </tex-math></inline-formula> ) of 3 to 100 <inline-formula xmlns:mml="http://www.w3.org/1998/Math/MathML" xmlns:xlink="http://www.w3.org/1999/xlink"> <tex-math notation="LaTeX">$\mu \text{m}$ </tex-math></inline-formula> were fabricated with nitrogen or argon plasma treatment. The width-normalized parasitic SD resistance ( <inline-formula xmlns:mml="http://www.w3.org/1998/Math/MathML" xmlns:xlink="http://www.w3.org/1999/xlink"> <tex-math notation="LaTeX">$R_{\mathrm{ SD}} {W}$ </tex-math></inline-formula> ) with the nitrogen plasma treatment was determined to be 11.3 <inline-formula xmlns:mml="http://www.w3.org/1998/Math/MathML" xmlns:xlink="http://www.w3.org/1999/xlink"> <tex-math notation="LaTeX">$\Omega \cdot $ </tex-math></inline-formula> cm, which was <italic xmlns:mml="http://www.w3.org/1998/Math/MathML" xmlns:xlink="http://www.w3.org/1999/xlink">ca.</i> 40% lower than that with the argon plasma treatment. This improvement in <inline-formula xmlns:mml="http://www.w3.org/1998/Math/MathML" xmlns:xlink="http://www.w3.org/1999/xlink"> <tex-math notation="LaTeX">$R_{\mathrm{ SD}} {W}$ </tex-math></inline-formula> resulted in higher mobility ( <inline-formula xmlns:mml="http://www.w3.org/1998/Math/MathML" xmlns:xlink="http://www.w3.org/1999/xlink"> <tex-math notation="LaTeX">$\mu $ </tex-math></inline-formula> ) in the nitrogen-plasma-treated SA IGZTO TFTs. A nitrogen-plasma-treated SA IGZTO TFT with <inline-formula xmlns:mml="http://www.w3.org/1998/Math/MathML" xmlns:xlink="http://www.w3.org/1999/xlink"> <tex-math notation="LaTeX">$L=10\,\,\mu \text{m}$ </tex-math></inline-formula> exhibited a high <inline-formula xmlns:mml="http://www.w3.org/1998/Math/MathML" xmlns:xlink="http://www.w3.org/1999/xlink"> <tex-math notation="LaTeX">$\mu $ </tex-math></inline-formula> of 27.2 cm <sup xmlns:mml="http://www.w3.org/1998/Math/MathML" xmlns:xlink="http://www.w3.org/1999/xlink">2</sup> /Vs.