Litcius/Paper detail

<scp>ZIF</scp>‐67 derived ternary <scp>NiMnCo</scp>‐based nanoporous carbon material for methanol oxidation reaction

Aqsa Saqib Lodhi, Naseem Iqbal, Tayyaba Nооr, Neelam Zaman, Junkuo Gao

2022International Journal of Energy Research13 citationsDOI

Abstract

Summary In this study, the electrocatalytic activity of mono‐metallic Co/NPC, bi‐metallic MnCo/NPC, and ternary NiMnCo/NPC in alkaline media for the methanol oxidation process was examined (MOR). These materials were produced using a simple solution mixing method and characterized using FTIR, EDX, SEM, XPS, TGA, and XRD. In a three‐electrode arrangement, on glassy carbon electrodes, the investigation of methanol oxidation for electrochemical activity of catalysts was carried in 1 M NaOH and 3 M CH 3 OH. Electrochemical studies included cyclic voltammetry (CV), chronoamperometry (CA), and electron impedance spectroscopy (EIS). The ternary NiMnCo/NPC composite, which has a peak current density of 147.85 mA/cm 2 at 0.8 potential and a scan rate of 50 mV/s among all the composites developed, is a promising catalyst for methanol electrocatalysis.

Topics & Concepts

ChronoamperometryCyclic voltammetryElectrocatalystDielectric spectroscopyMethanolTernary operationCatalysisElectrochemistryMaterials scienceNanoporousChemistryFourier transform infrared spectroscopyX-ray photoelectron spectroscopyInorganic chemistryNuclear chemistryChemical engineeringElectrodeNanotechnologyPhysical chemistryOrganic chemistryEngineeringProgramming languageComputer scienceElectrocatalysts for Energy ConversionSupercapacitor Materials and FabricationCatalytic Processes in Materials Science