Bridged and fused triazolic energetic frameworks with an azo building block towards thermally stable and applicable propellant ingredients
Qiong Yu, LI Feng-sheng, Ping Yin, Siping Pang, Richard J. Staples, Jean’ne M. Shreeve
Abstract
Smart assembly of an azo bridge into trinitromethyl triazoles, and controllable azo-trinitromethyl cyclization yield a novel green high-density energetic oxidizer and two fused nitrotriazolones with excellent thermal stabilities.
Topics & Concepts
PropellantYield (engineering)Block (permutation group theory)Bridge (graph theory)Materials scienceThermalThermal stabilityChemical engineeringComposite materialChemistryOrganic chemistryEngineeringThermodynamicsPhysicsMathematicsGeometryMedicineInternal medicineEnergetic Materials and CombustionThermal and Kinetic AnalysisFullerene Chemistry and Applications