Intramolecular C–N bond activation by a geometrically constrained P<sup>III</sup>-centre
Deependra Bawari, Solomon Volodarsky, Yael Ginzburg, Kuldeep Jaiswal, Pooja Joshi, Roman Dobrovetsky
Abstract
-centre into an N-C(O)H bond, an unstable phosphoranyl-formaldehyde intermediate is probably formed, which undergoes decarbonylation in the presence of a catalytic amount of HCl producing a hydrophosphorane.
Topics & Concepts
Intramolecular forceDecarbonylationChemistryFormaldehydeCatalysisStereochemistryCrystallographyOrganic chemistrySynthesis and characterization of novel inorganic/organometallic compoundsOrganoboron and organosilicon chemistryOrganometallic Complex Synthesis and Catalysis