Tuning photoelectron dynamic behavior of thiolate-protected MAu<sub>24</sub> nanoclusters <i>via</i> heteroatom substitution
Xueke Yu, Yuanze Sun, Wenwu Xu, Junyu Fan, Junfeng Gao, Xue Jiang, Yan Su, Jijun Zhao
Abstract
Heteroatom substitution of MAu 24 (SR) 18 nanoclusters enables precise tuning of their physicochemical properties at the single-atom level, including the electronic structures, vibrational properties, and photocarrier dynamic behavior.
Topics & Concepts
NanoclustersExcited stateHeteroatomChemical physicsMaterials scienceBand gapAtom (system on chip)ChemistryAtomic physicsNanotechnologyPhysicsOptoelectronicsEmbedded systemRing (chemistry)Organic chemistryComputer scienceNanocluster Synthesis and ApplicationsInorganic Chemistry and MaterialsAdvanced Nanomaterials in Catalysis