Modulated self-assembly of three flexible Cr(<scp>iii</scp>) PCPs for SO<sub>2</sub> adsorption and detection
Valeria B. López‐Cervantes, Dominic Bara, Ana Yañez-Aulestia, Eva Martínez‐Ahumada, Alfredo López‐Olvera, Yoarhy A. Amador‐Sánchez, Diego Solís-Ibarra, Elí Sánchez‐González, Ilich A. Ibarra, Ross S. Forgan
Abstract
Modulated self-assembly protocols are used to develop facile, HF-free syntheses of the archetypal flexible PCP, MIL-53(Cr), and novel isoreticular analogues MIL-53(Cr)-Br and MIL-53(Cr)-NO 2 , which adsorb and sense SO 2 .
Topics & Concepts
AdsorptionChemistrySelf-assemblyCombinatorial chemistryNanotechnologyCrystallographyMaterials sciencePhysical chemistryOrganic chemistryMetal-Organic Frameworks: Synthesis and ApplicationsGas Sensing Nanomaterials and SensorsMolecular Sensors and Ion Detection