Bio-inspired formal total synthesis of (±)-bisabosqual A
Xuanxuan Du, Hainan Liu, Yumeng Wu, Yu Tang
Abstract
A new approach was developed to construct a hexahydrobenzofurobenzopyran ring system by an oxa -[3+3], Diels–Alder reaction and oxidative aromatization. As a synthetic application, the bio-inspired formal synthesis of bisabosqual A was achieved.
Topics & Concepts
AromatizationChemistryFormal synthesisTotal synthesisRing (chemistry)Construct (python library)Combinatorial chemistryOxidative phosphorylationStereochemistryOrganic chemistryProgramming languageComputer scienceBiochemistryCatalysisPlant biochemistry and biosynthesisSynthetic Organic Chemistry MethodsChemical synthesis and alkaloids