Kinetic analysis to describe Co-operative redox enhancement effects exhibited by bimetallic Au–Pd systems in aerobic oxidation
Isaac T. Daniel, Liang Zhao, Donald Bethell, Mark Douthwaite, Samuel Pattisson, Richard J. Lewis, Ouardia Akdim, David Morgan, Steven McIntosh, Graham J. Hutchings
Abstract
Recent work has demonstrated that, for bimetallic Au–Pd systems, the rate of catalytic alcohol and formyl dehydrogenation (DH) is intrinsically linked to the rate of oxygen reduction (ORR) within the same system.
Topics & Concepts
Bimetallic stripDehydrogenationCatalysisRedoxChemistryOxygenOxygen reductionPhotochemistryCombinatorial chemistryInorganic chemistryOrganic chemistryPhysical chemistryElectrochemistryElectrodeCatalytic Processes in Materials ScienceElectrocatalysts for Energy ConversionOxidative Organic Chemistry Reactions