Mechanistic insights into the allylic oxidation of aliphatic compounds by tetraamido iron(<scp>v</scp>) species: A C–H <i>vs.</i> O–H bond activation
Monika, Azaj Ansari
Abstract
This work is based on a deep insight into a comparative study of C–H <italic>vs.</italic> O–H bond activation of allylic compound by the high valent iron complex. Our theoretical findings can help to design catalysts with better efficiency for catalytic reactions.
Topics & Concepts
ChemistryAllylic rearrangementCatalysisMedicinal chemistryStereochemistryCombinatorial chemistryOrganic chemistryCatalytic C–H Functionalization MethodsOxidative Organic Chemistry ReactionsMetal-Catalyzed Oxygenation Mechanisms