Interplay of a nitro group and metal ions: from coordinative binding to noncovalent semicoordination
Vitalii V. Suslonov, Natalia S. Soldatova, Daniil M. Ivanov, Павел С. Постников, Rosa M. Gomila, Antonio Frontera, Artem V. Semenov, Vadim Yu. Kukushkin, Nadezhda A. Bokach
Abstract
A place for M⋯O NO 2 semicoordination was found in the entire range of interactions that occur between a NO 2 group and metal sites.
Topics & Concepts
NitroChemistryGroup (periodic table)Non-covalent interactionsMetalMetal ions in aqueous solutionStereochemistryOrganic chemistryMoleculeHydrogen bondAlkylCrystallography and molecular interactionsCrystal structures of chemical compoundsChemical Thermodynamics and Molecular Structure