The synergistic effect of rigid and flexible substituents on insertion polymerization with α-diimine nickel and palladium catalysts
Zijuan Hai, Zhou Lu, Shuaikang Li, Zhong‐Yan Cao, Shengyu Dai
Abstract
The introduction of flexible cycloalkyl groups greatly enhanced the chain growth in the Ni( ii ) catalytic system and facilitated the insertion of polar monomers in the Pd( ii ) catalytic system.
Topics & Concepts
DiimineCatalysisPalladiumNickelMonomerChemistryPolymer chemistryPolymerizationPhotochemistryCombinatorial chemistryPolymerOrganic chemistryOrganometallic Complex Synthesis and CatalysisCarbon dioxide utilization in catalysisSynthetic Organic Chemistry Methods