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Molecularly imprinted polymer nanoparticle-carbon nanotube composite electrochemical gas sensor for highly selective and sensitive detection of methanol vapour

Todd Cowen, Sotirios Grammatikos, Michael Cheffena

2024The Analyst27 citationsDOI

Abstract

-propanol were found to be non-specific, and the response to water was negligible. This demonstrates an improvement over previous methanol gas sensors based on molecularly imprinted polymers. No response was observed with carbon nanotubes alone, and no selectivity was observed with non-imprinted equivalents of the nanoMIP sensor. The resulting device is by far the most practical MIP-based instrument for methanol gas sensing thus far described in the literature, being the only example capable of functioning at the necessary methanol vapour concentrations and at the required temperature and humidity. With the selectivity and sensitivity described and the simple design, the developed device provides a substantial advance in the field of molecularly imprinted gas sensors.

Topics & Concepts

MethanolCarbon nanotubeMolecularly imprinted polymerDetection limitMolecular imprintingMaterials scienceSelectivityPolymerNanoparticleComposite numberNanotechnologyChemical engineeringElectrochemistryElectrochemical gas sensorChromatographyChemistryOrganic chemistryComposite materialPhysical chemistryElectrodeCatalysisEngineeringAdvanced Chemical Sensor TechnologiesGas Sensing Nanomaterials and SensorsAnalytical Chemistry and Sensors
Molecularly imprinted polymer nanoparticle-carbon nanotube composite electrochemical gas sensor for highly selective and sensitive detection of methanol vapour | Litcius