Defect-Engineered 3D Nanostructured MoS<sub>2</sub> for Detection of Ammonia Gas at Room Temperature
Manoj K. Rajbhar, Sandip De, Gopal Sanyal, Avijit Kumar, Brahmananda Chakraborty, Shyamal Chatterjee
Abstract
Recent studies on nanostructured MoS 2 show promising performance in the detection of reducing gases like ammonia (NH 3 ). However, this material in the pristine form possesses limitations in terms of response, recovery, and repeatability over a long duration of time. Several attempts have been made to overcome these shortcomings by modifying it chemically to make a hybrid form or direct doping with other atoms. In this work, we demonstrate that suitable defect engineering of 3D nanostructured MoS 2 induced by a low energy ion beam can lead to a significantly improved performance of sensing NH 3 compared to the as-prepared one. Significant decreases in response and recovery times have been demonstrated at room temperature for the modified MoS 2 compared to its pristine form, which shows its best response only at a higher temperature of about 200 °C. A 3D nanoflower-like structure of MoS 2 was synthesized hydrothermally, which was coated on substrates, and then irradiated with 5 keV argon ions at different doses. While the ion beam-induced morphological modifications are observed via electron microscopic study, the surface defects are apparent in X-ray diffraction, Raman scattering, and X-ray spectroscopic studies. The ion beam-modified MoS 2 shows a higher electrical conductivity and water-repelling nature compared to the pristine one, which are complementary properties for better sensing performance. While Monte Carlo-based 3D ion-solid interaction simulation was used to support the morphological modifications and defect developments after ion irradiation, the sensing mechanism and change in conductivity were successfully explained using density functional theory-based simulations.