Zirconium-based metal–organic frameworks: the relation between linker connectivity, structure stability, and catalytic activity towards organophosphates
Daniel Bůžek, Jan Hynek, Matouš Kloda, Veronika Zlámalová, Petr Bezdička, Slavomír Adamec, Kamil Lang, Jan Demel
Abstract
The stability of MOFs in aqueous environments is influenced by the linker topicity rather than by the connectivity. Only MIP-200 survives the alkaline environment.
Topics & Concepts
LinkerZirconiumCatalysisAqueous solutionMetal-organic frameworkMetalChemistryMaterials scienceChemical engineeringInorganic chemistryOrganic chemistryComputer scienceOperating systemAdsorptionEngineeringMetal-Organic Frameworks: Synthesis and ApplicationsMolecular Sensors and Ion DetectionCrystallography and molecular interactions