Palladium-catalyzed C(sp<sup>3</sup>)–H nitrooxylation of masked alcohols
Yuan Xue, Ruo-Bing Zhou, Jun Luo, Bingcheng Hu, Zhong‐Quan Liu, Chao Jiang
Abstract
C-H activation and selectfluor acts as the oxidant. The reaction tolerates a variety of functional groups and shows good selectivity for β-C-H nitrooxylation of alcohols.
Topics & Concepts
ChemistryPalladiumSelectfluorCatalysisSelectivityOximeMedicinal chemistryOrganic chemistryFunctional groupPolymerCatalytic C–H Functionalization MethodsSynthesis and Catalytic ReactionsOxidative Organic Chemistry Reactions