Understanding Cu(<scp>i</scp>) local environments in MOFs <i>via</i><sup>63/65</sup>Cu NMR spectroscopy
Wanli Zhang, Bryan E. G. Lucier, Victor V. Terskikh, Shoushun Chen, Yining Huang
Abstract
Cu solid-state NMR spectroscopy and DFT calculations for molecular-level characterization of Cu(i) centers in MOFs, along with the potential of this protocol for investigating a wide variety of MOF structural changes and processes important for practical applications. This approach has broad applications for examining Cu(i) centers in other weight-dilute systems.
Topics & Concepts
Nuclear magnetic resonance spectroscopySpectroscopyCopperChemistryCrystallographyStereochemistryPhysicsOrganic chemistryQuantum mechanicsMetal-Organic Frameworks: Synthesis and ApplicationsInorganic Fluorides and Related CompoundsMagnetism in coordination complexes