Sulfur-Donor Solvents Strongly Coordinate Pb<sup>2+</sup> in Hybrid Organic–Inorganic Perovskite Precursor Solutions
J. Clay Hamill, Oluwaseun Romiluyi, S. Thomas, Jacquelyn Cetola, Jeffrey Schwartz, Michael F. Toney, Paulette Clancy, Yueh‐Lin Loo
Abstract
Strong coordination between Lewis-basic processing additives and the Lewis-acidic lead halide in hybrid organic–inorganic perovskite (HOIP) precursor solutions is required to solubilize the lead halide, and subsequently access the appropriate crystallization kinetics and attain the desired morphology of perovskite active layers. While oxygen-donor solvents and additives, such as dimethylformamide and dimethyl sulfoxide, are widely used for perovskite processing, we demonstrate here that “soft” sulfur-donor solvents exhibit stronger coordination to the “borderline soft” Lewis acid Pb<sup>2+</sup> center of PbI<sub>2</sub> relative to “hard” O-donor solvents in the precursor solution. The stronger coordination of S-donor solvents compared to O-donor solvents to Pb<sup>2+</sup> implies that such compounds can be useful additives to HOIP precursor solutions. Density-functional calculations of the enthalpy change resulting from the coordination of solvents to Pb<sup>2+</sup> provide direct numerical comparison of the strength of O-donor and S-donor coordination with Pb<sup>2+</sup> and expands the library of candidate S-donor compounds. Our results provide a roadmap for processing additive selection and expand the previously limited choice of perovskite processing additives to include strongly coordinating S-donor compounds.