Simulation of Optimized High-Current Tandem Solar-Cells With Efficiency Beyond 41%
Mohamed Mousa, Fathy Z. Amer, Roaa I. Mubarak, Ahmed Saeed
Abstract
Two-terminalt and tandem solar-cells have a high efficiency of power conversion. One of their main limitations is the operating current density as the two-terminal tandem solar-cell is equivalent to electrically connected series subcells. Increasing the top absorber layer’s thickness will lead to an increase in the top subcell current and a decrease in the bottom subcell’s current. The subcell with the minimum current forces the tandem cell to operate at its value, limiting the overall performance. In this paper, a proposed solution for such a problem is introduced using a bottom subcell consisting of germanium-telluride (GeTe), which gives a high current and matches the top subcell at a thicker absorber layer. A proposal of three different tandem cells with perovskite (MAPbI <sub xmlns:mml="http://www.w3.org/1998/Math/MathML" xmlns:xlink="http://www.w3.org/1999/xlink">3</sub> )/CIGS, perovskite (MAPbI <sub xmlns:mml="http://www.w3.org/1998/Math/MathML" xmlns:xlink="http://www.w3.org/1999/xlink">3</sub> )/GeTe, and perovskite (MAPbI <sub xmlns:mml="http://www.w3.org/1998/Math/MathML" xmlns:xlink="http://www.w3.org/1999/xlink">3-x</sub> Cl <sub xmlns:mml="http://www.w3.org/1998/Math/MathML" xmlns:xlink="http://www.w3.org/1999/xlink">x</sub> )/GeTe have been presented. The proposed perovskite (MAPbI <sub xmlns:mml="http://www.w3.org/1998/Math/MathML" xmlns:xlink="http://www.w3.org/1999/xlink">3</sub> )/CIGS has an efficiency of 30.52%, whereas the replacement of the CIGS bottom subcell by GeTe led to a significant enhancement of the efficiency to reach 35.9%. High efficiency of 41.7% is obtained by replacing the perovskite (MAPbI <sub xmlns:mml="http://www.w3.org/1998/Math/MathML" xmlns:xlink="http://www.w3.org/1999/xlink">3</sub> ) top subcell with perovskite (MAPbI <sub xmlns:mml="http://www.w3.org/1998/Math/MathML" xmlns:xlink="http://www.w3.org/1999/xlink">3-x</sub> Cl <sub xmlns:mml="http://www.w3.org/1998/Math/MathML" xmlns:xlink="http://www.w3.org/1999/xlink">x</sub> ). A modified numerical algorithm is proposed to obtain the optimum thickness of the top subcell to achieve higher power-conversion efficiency. The performance evaluation and simulation of the designed tandem cells were carried out using SCAPS-1D. The temperature effects on the proposed cells have been encountered in simulation. The results show that the proposed tandem solar-cells have comparable performance and higher efficiencies relative to the published works.