Dithiocarbamate mediated thioamidation <i>via</i> C–C single bond cleavage of styrene: study of the protocol in decarbonylative and decarboxylative thioamidations
Debabrata Patra, Amit Saha
Abstract
Styrene undergoes transition-metal-free dealkenylative thioamidations by dithiocarbamate anions under aerial conditions. Decarbonylative and decarboxylative thioamidations have also been tested on benzaldehyde, toluene and benzoic acid.
Topics & Concepts
ChemistryDithiocarbamateTolueneStyreneDecarbonylationBenzaldehydeBenzoic acidCleavage (geology)Medicinal chemistryBond cleavagePolymer chemistryOrganic chemistryCatalysisCopolymerPolymerEngineeringFracture (geology)Geotechnical engineeringSynthesis and Reactivity of Sulfur-Containing CompoundsSulfur-Based Synthesis TechniquesPhenothiazines and Benzothiazines Synthesis and Activities